Esters in Synthetic
Lubricants
History
Dr. Hermann Zorn[1]
of
I.G. Farben Industries in Germany began[when?]
to search for lubricants with the properties of natural oils
but without the tendencies to gel or gum when used in an
engine environment. His work[2][3]
led to the preparation of over 3500
esters in the late 1930s and early 1940s including
diesters,
polyolesters, and banana oil. During the same time
period in the United States, Dr.
William Albert Zismann[4]
working at the
U.S. Naval Research Laboratory (NRL) was also
synthesizing esters, especially diesters.
The first real synthetic engine oils
appeared for aircraft engines in World War II concurrently
in Germany and in the United States. The motivation in
Germany may be related primarily to resource issues, but
also to functional performance requirements. The base oils
for aircraft engines in Germany were based on a blend of an
adipic acid ester with a poly(ethylene) oil[5],
e.g., polymerized olefins/ethylene. Because synthetic oils
made engine starting in winter easier and significantly
decreased soot deposits in oil radiators, the
United States Army Air Forces adopted polyglycols (polypropylene
glycol monobutylethers) beginning in March 1944.[6][7]
http://en.wikipedia.org/wiki/Synthetic_oil
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